Officers responding to the All Stars Bar and Grill in Warwick at about 1:15 a.m. found the victims in the parking lot with stab wounds to the neck and torso.
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The two were taken to the hospital and are in stable condition.
The firefighter, 35-year-old John Decarlo of Brooklyn, is facing multiple charges, including assault with intent to commit murder.
Decarlo's attorney says his client is an honorably discharged Marine.
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Four other men, all Rhode Island residents, were charged with disorderly conduct.
Decarlo was held on $50,000 bond at his arraignment. He did not enter a plea.
(The Associated Press contributed to this report.)
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