Police said Saturday that 24-year-old Jarret Heitmann and 22-year-old Makayla Stilwell were spotted in Pine Bush, about 85 miles north of New York City.
The home invasion occurred at approximately 3:44 am in Bloomingburg, with the suspect or suspects entering a home on Altamont Road and taking personal effects.
One resident suffered minor injuries, and the investigation is ongoing.
Police in Sullivan County in Tennessee say Heitmann and Stilwell kidnapped a woman and shot a man in the chest on Tuesday, then fled.
The shooting victim, 34-year-old Dustin Bishop, was hospitalized for treatment of his injuries.
The Tennessee Bureau of Investigation is offering a $1,000 reward for information leading to the arrest of each suspect.