Saeed Ahmad, 23, is accused of crashing into a concrete barrier last week on the Gowanus Expressway killing 25-year-old Harleen Grewal.
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In exclusive video obtained by Eyewitness News, you can see a man hailing a cab in the middle of the expressway while Grewal burned to death.
Exclusive: Man hails cab while girlfriend dies in car fire
Ahmed was later found at Maimonides Medical Center, where he was treated for burns to his neck, arms and legs.
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He was arrested and facing charges of second degree manslaughter, criminally negligent homicide, leaving the scene of an accident, aggravated unlicensed operator and speeding.
Ahmad will be arraigned in Brooklyn.