It happened just before 5 p.m. near the corner of 6th Avenue and 1st Street in Park Slope.
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Responding officers found a 31-year-old man with a gunshot wound to the head in the driver's seat of a white 2019 Chevrolet Impala.
EMS responded to the location and transported the victim to New York-Presbyterian Brooklyn Methodist Hospital, where he was subsequently pronounced deceased.
There are no arrests, and the investigation is ongoing.
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The identity of the victim is pending proper family notification.
Police believe the shooter was in a white Acura with New Jersey plates.
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