The crash happened before 9:30 a.m. and police say Route 132 will be closed between Barger and Wildwoods streets for the investigation.
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Five high school-aged students were on the bus at the time of the crash and were taken to Westchester Medical Center with non-life-threatening injuries.
The bus driver was taken to the hospital for observation.
The driver of the other vehicle, an SUV, is in critical condition at Westchester Medical Center after EMS found him unconscious inside the car.
Police were investigating if the driver suffered a medical emergency or not but the cause of the crash remains under investigation.
Few other details were released.
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