Destiny Waite, 28, was charged with criminal attempt to commit murder, first-degree arson and first degree assault.
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The blaze was reported at a five-story apartment building in Hartford around 1:20 a.m. Sunday, fire Chief James Errickson said.
Authorities identified the man who died as Jerome Kyser, 50, who lived in the building.
Mayor Luke Bronin's office said 31 residents were treated at a hospital and more than 60 families were displaced.
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The city's Health and Human Services agency opened a temporary shelter and is helping the families find other housing
Waite was in custody on $900,000 bail.
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